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A Graffiti ‘Shield’!

Posted by Science Oxford on August 19, 2009 | comments

Although, there are already several anti-graffiti paints out on the market this innovative new salt mixture claims to be a huge improvement.
Read on to find out more:

Graf­fiti mars many a his­tor­ic land­mark, but it can only be erased—if at all—us­ing caus­tic so­lu­tions that risk dam­ag­ing the un­der­ly­ing sur­face.

A new “breath­able” wall coat­ing, though, of­fers ef­fi­cient, all-round pro­tec­tion against at­tacks by spray­can hooli­gans, re­search­ers claim.

It takes sec­onds to spray on graf­fiti, but hours or weeks to re­move, es­pe­cially from the po­rous nat­u­ral stone or brick­work that char­ac­ter­ize the ma­jor­ity of his­tor­ic mon­u­ments. The paint seeps deep in­to the pores and can be­come un­re­moveable even with a pres­sure hose or pow­er­ful cleans­ing sol­vents.

Of­ten noth­ing will do the trick short of chem­i­cals that eat away at a ven­er­a­ble wall.

Some an­ti-graf­fiti coat­ings have al­ready been on the mar­ket for sev­er­al years. They cre­ate a wa­ter-re­pel­lent seal that shuts the pores. That helps keep the paint from stick­ing to the sur­face, so that it easily comes off.

But these coat­ings al­so seal out air and lock in mois­ture, ac­cord­ing to An­dré Laschewsky, a re­search­er with the Fraun­ho­fer In­sti­tute for Ap­plied Pol­y­mer Re­search in Pots­dam, Ger­many. That, he said, leaves the sur­face vul­ner­a­ble to mold or the de­vel­op­ment of un­sightly salt de­posits. More­o­ver, he added, these coat­ings are them­selves hard to re­move, and thus flout a prin­ci­ple dear to con­serva­t­ion­ist­s—that any changes to a his­tor­ic mon­u­ment should be re­vers­i­ble.

The trou­ble, Laschewsky said, is that a suc­cess­ful coat­ing must meet “con­flict­ing re­quire­ments.” It must­n’t seal the sur­face en­tire­ly, yet it has to keep the paint from get­ting in. It needs to re­sist weath­er­ing and wip­ing down, yet be easily re­moveable when it’s nec­es­sary.

As part of a Eu­ro­pe­an Un­ion-sponsored proj­ect, Laschewsky and col­leagues with the Pol­ish Acad­e­my of Sci­ences de­vel­oped a pol­y­mer coat­ing that they claim sat­is­fies these de­mands. Pol­y­mers are a large class of com­pounds con­sist­ing of large mo­le­cules made up of smaller re­peat­ing un­its, as in plas­tics.

The newly cre­ated pol­y­mer film seals the pores on a build­ing sur­face so as to block the un­wanted paint, Laschewsky ex­plained. At the same time, the new coat­ing has its own, much smaller “micro-pores,” which cre­ate a wa­ter-re­pel­lent bar­ri­er that al­lows air to reach the build­ing.

The coat­ing is re­moveable us­ing a salt so­lu­tion that mod­i­fies its chem­i­cal com­po­si­tion and al­lows it to be washed off, he added. In a proj­ect co­or­di­nated by the Labein Founda­t­ion, a non­prof­it re­search cen­ter in Bil­boa, Spain, and the Ger­man Fed­er­al In­sti­tute for Ma­te­ri­als Re­search and Test­ing, Laschewsky and part­ners coat­ed sam­ples of an­cient stone and brick and re­peat­edly cov­ered them with graf­fiti—which, they said, com­pletely washed off each time.

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